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It is notable that he has a tendency to ridicule, make enemies out of, and/or bring to shame a very large number of celebrities that are shown in a poor light within the show.
He became terribly depressed and hopeless when Wendy broke up with him, and he briefly joined the Goth Kids.
Stan (as well as the rest of the boys from 4th grade) also went to Mexico and managed to get the Mexican Space Program to take an Orca to the moon in a bid to save it (with all the kids in South Park having been led to believe he was a killer whale from the moon) in "Free Willzyx".
In "Two Days Before the Day After Tomorrow", after he and Cartman crash a boat into a beaver dam and swim to shore, seeing the boat blow up, Stan says, "I hope we didn't hurt any beavers." In "Fun with Veal" he briefly turned to vegetarianism, but he quickly gave it up when he was plagued by a disease that literally "turned him into a pussy", sprouting actual vaginas on his body, a disease called Vaginitus.
Stan is often preachy and very critical of popular trends.
This is evident in "Cherokee Hair Tampons", when he challenged the character Miss Information and her shop of alternative medicine, in "Super Best Friends", when he helped battle David Blaine's suicidal cult, and in "The Biggest Douche in the Universe" where he accuses the psychic medium, John Edward, of being a fake.